SELECT * FROM question_mgmt as q WHERE id=3152 AND status=1 SELECT id,question_no,question,chapter FROM question_mgmt as q WHERE courseId=2 AND subId=9 AND chapterId=52 and ex_no='1' AND status=1 ORDER BY CAST(question_no AS UNSIGNED) CBSE Free NCERT Solution of 11th chemistry The p Block Elements suggest reasons why the b f bond lengths in bf3 1

Question:

Suggest reasons why the B-F bond lengths in BF3 (130 pm) and BF-4(143 pm) differ.

Answer:

The B-F bond length in BF3 is shorter than the B-F bond length in BF-4 . BF3 BF3 is an electron-deficient species. With a vacant p-orbital on boron, the fluorine and boron atoms undergo pπ-pπ back bonding to remove this deficiency. This imparts a double-bond character to the B-F bond.

This double-bond character causes the bond length to shorten in BF3(130 pm). However, when BF3 coordinates with the fluoride ion, a change in hybridisation from sp2 (in BF3) to sp3 (in BF-4) occurs. Boron now forms 4 σ  bonds and the double-bond character is lost. This accounts for a B-F bond length of 143 pm in BF-4 ion.


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