SELECT * FROM question_mgmt as q WHERE id=2020 AND status=1 SELECT id,question_no,question,chapter FROM question_mgmt as q WHERE courseId=3 AND subId=9 AND chapterId=66 and ex_no='2' AND status=1 ORDER BY CAST(question_no AS UNSIGNED) CBSE Free NCERT Solution of 12th chemistry Alcohols Phenols and Ethers illustrate with examples the limitations of willia

Question:

Illustrate with examples the limitations of Williamson synthesis for the preparation of certain types of ethers.

Answer:

The reaction of Williamson synthesis involves SN2 attack of an alkoxide ion on a primary alkyl halide.

But if secondary or tertiary alkyl halides are taken in place of primary alkyl halides, then elimination would compete over substitution. As a result, alkenes would be produced. This is because alkoxides are nucleophiles as well as strong bases. Hence, they react with alkyl halides, which results in an elimination reaction.


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