SELECT * FROM question_mgmt as q WHERE id=1787 AND status=1 SELECT id,question_no,question,chapter FROM question_mgmt as q WHERE courseId=3 AND subId=9 AND chapterId=58 and ex_no='2' AND status=1 ORDER BY CAST(question_no AS UNSIGNED) CBSE Free NCERT Solution of 12th chemistry Electrochemistry define conductivity and molar conductivity for the

Question:

Define conductivity and molar conductivity for the solution of an electrolyte. Discuss their variation with concentration.

Answer:

Conductivity of a solution is defined as the conductance of a solution of 1 cm in length and area of cross-section 1 sq. cm. The inverse of resistivity is called conductivity or specific conductance. It is represented by the symbol k. If p is resistivity, then we can write:

k = 1 / p

The conductivity of a solution at any given concentration is the conductance (G) of one unit volume of solution kept between two platinum electrodes with the unit area of cross-section and at a distance of unit length.

i.e., 

(Since a = 1, l = 1)

Conductivity always decreases with a decrease in concentration, both for weak and strong electrolytes. This is because the number of ions per unit volume that carry the current in a solution decreases with a decrease in concentration.

 

Molar conductivity:

Molar conductivity of a solution at a given concentration is the conductance of volume V of a solution containing 1 mole of the electrolyte kept between two electrodes with the area of cross-section A and distance of unit length.

Now, l = 1 and A = V (volume containing 1 mole of the electrolyte).

Am = kV

Molar conductivity increases with a decrease in concentration. This is because the total volume V of the solution containing one mole of the electrolyte increases on dilution.

The variation of  Am with  for strong and weak electrolytes is shown in the following plot:


< Previous Question

Next Question >

SELECT ex_no,question,question_no,id,chapter FROM question_mgmt as q WHERE courseId='3' AND subId='9' AND ex_no!=0 AND status=1 and id!=1787 ORDER BY views desc, last_viewed_on desc limit 0,10

  • Popular questions of class 12 Chemistry

SELECT ex_no,question,question_no,id,chapter FROM question_mgmt as q WHERE courseId='3' AND subId='9' AND ex_no!=0 AND status=1 and id!=1787 ORDER BY last_viewed_on desc limit 0,10

  • Recently Viewed Questions of Class 12 Chemistry

Comments

  • Answered by Ekta Mehta
  • 4 months ago

Taking Screenshots on your Samsung Galaxy M31s is very easy and quick.

  • Answered by Ekta Mehta
  • 4 months ago

Taking Screenshots on your Samsung Galaxy M31s is very easy and quick.

  • Answered by Ekta Mehta
  • 4 months ago

Taking Screenshots on your Samsung Galaxy M31s is very easy and quick.

Comment(s) on this Question


NCERT Solutions

Quick Links

Resources

Support