SELECT * FROM question_mgmt as q WHERE id=1231 AND status=1 SELECT id,question_no,question,chapter FROM question_mgmt as q WHERE courseId=2 AND subId=9 AND chapterId=42 and ex_no='1' AND status=1 ORDER BY CAST(question_no AS UNSIGNED) CBSE Free NCERT Solution of 11th chemistry Some Basic Concepts of Chemistry determine the molecular formula of an oxide of iro

Question:

Determine the molecular formula of an oxide of iron in which the mass per cent of iron and oxygen are 69.9 and 30.1 respectively. Given that the molar mass of the oxide is 159.69 g mol–1.

Answer:

From the available data Percentage of iron = 69.9

Percentage of oxygen= 30.1

Total percentage of iron & oxygen= 69.9+30.1= 100% 

 

Step 1 calculation of simplest whole number ratios of the elements

Element

Percentage

Atomic mass

Atomic ratio

Simplest ratio

Simplest whole no ratio

Fe

69.9

55.84

69.9/55.84=1.25

1.25= 1

2

O

30.1

16

30.1/16 = 1.88

1.88=1.5

3

 

Step 2  Writing the empirical formula of the compound

The empirical formula of the compound = Fe2 O3

 

Step 3 determination of molecular formula of the compound

 

Empirical formula mass = 2 X69.9 + 3 X16=187.8 amu

 

Molecular mass of oxide= 159.69g/mol(given)

Now we know molecular formula = n x Empirical formula

 

And n= molecular mass / empirical formula mass= 159.69/187.8 = 0.85 = approx 1

 

Therefore molecular formula = n x empirical formula

 

=1 x(Fe2O3) = Fe2O3

 

The molecular formula of the oxide is Fe2O3


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