SELECT * FROM question_mgmt as q WHERE id=1745 AND status=1 SELECT id,question_no,question,chapter FROM question_mgmt as q WHERE courseId=3 AND subId=9 AND chapterId=56 and ex_no='2' AND status=1 ORDER BY CAST(question_no AS UNSIGNED)
Niobium crystallises in body-centred cubic structure. If density is 8.55 g cm-3, calculate atomic radius of niobium using its atomic mass 93 u.
Given Density = 8.55 gcm-3
Let the length of the edge = a cm
Number of atoms per unit cell, Z = 2
Atomic mass M = 93 u
From the formula , density = ZxM/a3 x N0, we get
8.55 = 2 x 93/a3 x 6.022 x 1023 = 36.12 x 10-24 cm3
Now edge length,a = (36.12 x 10-24)1/3 = 3.306 x 10-8 cm
Now radius in body centered cubic, r = √3/4 a
Putting the value of a, we get .r = 1.431 x 10-10 m
The following results have been obtained during the kinetic studies of the reaction: 2A + B → C + D
Experiment |
A/ mol L - 1 |
B/ mol L - 1 |
Initial rate of formation of D/mol L - 1 min - 1 |
I | 0.1 | 0.1 |
6.0 × 10 - 3 |
II | 0.3 | 0.2 |
7.2 × 10 - 2 |
III | 0.3 | 0.4 |
2.88 × 10 - 1 |
IV | 0.4 | 0.1 |
2.40 × 10 - 2 |
Determine the rate law and the rate constant for the reaction.
Vapour pressure of pure acetone and chloroform at 328 K are 741.8 mm Hg and 632.8 mm Hg respectively. Assuming that they form ideal solution over the entire range of composition, plot ptotal' pchloroform' and pacetoneas a function of xacetone. The experimental data observed for different compositions of mixture is.
100 ×xacetone |
0 | 11.8 | 23.4 | 36.0 | 50.8 | 58.2 | 64.5 | 72.1 |
pacetone /mm Hg |
0 | 54.9 | 110.1 | 202.4 | 322.7 | 405.9 | 454.1 | 521.1 |
pchloroform/mm Hg |
632.8 | 548.1 | 469.4 | 359.7 | 257.7 | 193.6 | 161.2 | 120.7 |
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