Home
NCERT Solution
Class 11
Chemistry
Thermodynamics
calculate the enthalpy change on freezing of 1 0 m...

Question:
Calculate the enthalpy change on freezing of 1.0 mol of water at 10.0°C to ice at -10.0°C. Δ_fusH = 6.03 kJ mol^-1 at 0°C.

C_p[H₂O(l)] = 75.3 J mol^-1 K^-1

C_p[H₂O(s)] = 36.8 J mol^-1 K^-1

Answer:

Total enthalpy change involved in the transformation is the sum of the following changes:

(a) Energy change involved in the transformation of 1 mol of water at 10°C to 1 mol of water at 0°C.

(b) Energy change involved in the transformation of 1 mol of water at 0° to 1 mol of ice at 0°C.

Total ΔH = C_p [H₂OCI] ΔT + ΔH_freezing + C_p[H₂O_(s)] ΔH

= (75.3 J mol^-1 K^-1) (0 - 10)K + (-6.03 × 10³ J mol^-1) + (36.8 J mol^-1 K^-1) (-10 - 0)K

= -753 J mol^-1- 6030 J mol^-1- 368 J mol^-1

= -7151 J mol^-1

= -7.151 kJ mol^-1

Hence, the enthalpy change involved in the transformation is -7.151 kJ mol^-1.

1
0
0
Report?

Report a problem on Specifications:

Email id:

Comments

< Previous Question

Next Question >

SELECT ex_no,question,question_no,id,chapter FROM question_mgmt as q WHERE courseId='2' AND subId='9' AND ex_no!=0 AND status=1 and id!=2796 ORDER BY views desc, last_viewed_on desc limit 0,10

Popular questions of class 11 Chemistry

The mass of an electron is 9.1 × 10^–31 kg. If its K.E. is 3.0 × 10^–25 J, calculate its wavelength.

Calculate the amount of carbon dioxide that could be produced when

(i) 1 mole of carbon is burnt in air.

(ii) 1 mole of carbon is burnt in 16 g of dioxygen.

(iii) 2 moles of carbon are burnt in 16 g of dioxygen.

Calculate the wavelength of an electron moving with a velocity of 2.05 × 10⁷ ms^–1.

Balance the following redox reactions by ion – electron method :

(a) MnO₄^–(aq) + I^–(aq) → MnO_{2 (s)} + I_2(s) (in basic medium)

(b) MnO₄ ^– (aq) + SO_{2 (g)}→ Mn²⁺ (aq) + HSO₄^– (aq) (in acidic solution)

(d) Cr₂O₇ ^2– + SO_2(g) → Cr³⁺ _(aq) + SO₄^2–(aq) (in acidic solution)

In a process, 701 J of heat is absorbed by a system and 394 J ofwork is done by the system. What is the change in internal energy for the process?

What will be the minimum pressure required to compress 500 dm³ of air at 1 bar to 200 dm³ at 30°C?

In a reaction A + B2 → AB2 Identify the limiting reagent, if any, in the following reaction mixtures.

(i) 300 atoms of A + 200 molecules of B

(ii) 2 mol A + 3 mol B

(iii) 100 atoms of A + 100 molecules of B

(iv) 5 mol A + 2.5 mol B

(v) 2.5 mol A + 5 mol B

At 0°C, the density of a certain oxide of a gas at 2 bar is same as that of dinitrogen at 5 bar. What is the molecular mass of the oxide?

Which one of the following will have largest number of atoms?

(i) 1 g Au (s)

(ii) 1 g Na (s)

(iii) 1 g Li (s)

(iv) 1 g of Cl2(g)

Density of a gas is found to be 5.46 g/dm³ at 27 °C at 2 bar pressure. What will be its density at STP?

SELECT ex_no,question,question_no,id,chapter FROM question_mgmt as q WHERE courseId='2' AND subId='9' AND ex_no!=0 AND status=1 and id!=2796 ORDER BY last_viewed_on desc limit 0,10

Recently Viewed Questions of Class 11 Chemistry

An alkene ‘A’ contains three C – C, eight C – H σ bonds and one C – C π bond. ‘A’ on ozonolysis gives two moles of an aldehyde of molar mass 44 u. Write IUPAC name of ‘A’.

Dinitrogen and dihydrogen react with each other to produce ammonia according to the following chemical equation:

N2(g) + H2(g) → 2NH3(g)

(i) Calculate the mass of ammonia produced if 2.00 × 103 g dinitrogen reacts with 1.00 × 103 g of dihydrogen.

(ii) Will any of the two reactants remain unreacted?

(iii) If yes, which one and what would be its mass?

What do you understand by isoelectronic species? Name a species that will be isoelectronic with each of the following atoms or ions.

(i) F^–

(ii) Ar

(iii) Mg²⁺

(iv) Rb⁺

Describe the change in hybridisation (if any) of the Al atom in the following reaction.

0.3780 g of an organic chloro compound gave 0.5740 g of silver chloride in Carius estimation. Calculate the percentage of chlorine present in the compound.

:(i) Write the electronic configurations of the following ions: (a) H^–(b) Na⁺ (c) O^2–(d) F^–

(ii) What are the atomic numbers of elements whose outermost electrons are represented by (a) 3s¹(b) 2p³ and (c) 3p⁵?

(iii) Which atoms are indicated by the following configurations?

(a) [He] 2s¹ (b) [Ne] 3s² 3p³ (c) [Ar] 4s² 3d¹.

Arrange benzene, n-hexane and ethyne in decreasing order of acidic behaviour. Also give reason for this behaviour.

Discuss the pattern of variation in the oxidation states of
(i) B to Tl and (ii) C to Pb.

Explain the principle of paper chromatography.

What is the number of photons of light with a wavelength of 4000 pm that provide 1 J of energy?

Question:
Calculate the enthalpy change on freezing of 1.0 mol of water at 10.0°C to ice at -10.0°C. Δ_fusH = 6.03 kJ mol^-1 at 0°C.

C_p[H₂O(l)] = 75.3 J mol^-1 K^-1

C_p[H₂O(s)] = 36.8 J mol^-1 K^-1

< Previous Question

Next Question >

Popular questions of class 11 Chemistry

Recently Viewed Questions of Class 11 Chemistry

Comments

Comment(s) on this Question

Important links

Quick Links

Resources

Support

Question: Calculate the enthalpy change on freezing of 1.0 mol of water at 10.0°C to ice at -10.0°C. ΔfusH = 6.03 kJ mol-1 at 0°C. Cp[H2O(l)] = 75.3 J mol-1 K-1 Cp[H2O(s)] = 36.8 J mol-1 K-1

< Previous Question

Next Question >

Popular questions of class 11 Chemistry

Recently Viewed Questions of Class 11 Chemistry

Comments

Comment(s) on this Question

Important links

Quick Links

Resources

Support

Question:
Calculate the enthalpy change on freezing of 1.0 mol of water at 10.0°C to ice at -10.0°C. Δ_fusH = 6.03 kJ mol^-1 at 0°C.

C_p[H₂O(l)] = 75.3 J mol^-1 K^-1

C_p[H₂O(s)] = 36.8 J mol^-1 K^-1