Why is Wurtz reaction not preferred for | Class 11 Chemistry Chapter Hydrocarbons, Hydrocarbons NCERT Solutions

The mass of an electron is 9.1 × 10^–31 kg. If its K.E. is 3.0 × 10^–25 J, calculate its wavelength.

Calculate the amount of carbon dioxide that could be produced when

(i) 1 mole of carbon is burnt in air.

(ii) 1 mole of carbon is burnt in 16 g of dioxygen.

(iii) 2 moles of carbon are burnt in 16 g of dioxygen.

Calculate the wavelength of an electron moving with a velocity of 2.05 × 10⁷ ms^–1.

Balance the following redox reactions by ion – electron method :

(a) MnO₄ ^– (aq) + I ^– (aq) → MnO_{2 (s)} + I_2(s) (in basic medium)

(b) MnO₄ ^– (aq) + SO_{2 (g)} → Mn²⁺ (aq) + HSO₄^– (aq) (in acidic solution)

(c) H₂O_{2 (aq)} + Fe ²⁺ (aq) → Fe³⁺ (aq) + H₂O (l) (in acidic solution)

(d) Cr₂O₇ ^2– + SO_2(g) → Cr³⁺ _(aq) + SO₄^2– (aq) (in acidic solution)

In a process, 701 J of heat is absorbed by a system and 394 J ofwork is done by the system. What is the change in internal energy for the process?

What will be the minimum pressure required to compress 500 dm³ of air at 1 bar to 200 dm³ at 30°C?

In a reaction A + B2 → AB2 Identify the limiting reagent, if any, in the following reaction mixtures.

(i) 300 atoms of A + 200 molecules of B

(ii) 2 mol A + 3 mol B

(iii) 100 atoms of A + 100 molecules of B

(iv) 5 mol A + 2.5 mol B

(v) 2.5 mol A + 5 mol B

At 0°C, the density of a certain oxide of a gas at 2 bar is same as that of dinitrogen at 5 bar. What is the molecular mass of the oxide?

Which one of the following will have largest number of atoms?

(i) 1 g Au (s)

(ii) 1 g Na (s)

(iii) 1 g Li (s)

(iv) 1 g of Cl2(g)

Density of a gas is found to be 5.46 g/dm³ at 27 °C at 2 bar pressure. What will be its density at STP?

Elements of group 14

(a) exhibit oxidation state of +4 only

(b) exhibit oxidation state of +2 and +4

(c) form M^2-and M⁴⁺ion

(d) form M²⁺and M⁴⁺ions

For the reaction at 298 K,

2A + B → C

ΔH = 400 kJ mol^-1and ΔS = 0.2 kJ K^-1mol^-1

At what temperature will the reaction become spontaneous considering ΔH and ΔS to be constant over the temperature range?

Arrange benzene, n-hexane and ethyne in decreasing order of acidic behaviour. Also give reason for this behaviour.

The type of hybridisation of boron in diborane is

(a) sp    (b) sp²   (c) sp³    (d) dsp²

A sample of pure PCl5 was introduced into an evacuated vessel at 473 K. After equilibrium was attained, concentration of PCl5 was found to be 0.5 × 10^–1 mol L^–1. If value of Kc is 8.3 × 10^–3, what are the concentrations of PCl₃ and Cl₂ at equilibrium?

PCl₅ (g) ↔ PCl₃ (g) + Cl₂(g)

If the starting material for the manufacture of silicones is RSiCl₃, write the structure of the product formed.

For an isolated system, ΔU = 0, what will be ΔS?

What is the minimum volume of water required to dissolve 1g of calcium sulphate at 298 K? (For calcium sulphate, K_sp is 9.1 x 10^-6).

Given

N₂(g) + 3H₂(g) → 2NH₃(g) ; Δ_rH⁰ = –92.4 kJ mol^–1

What is the standard enthalpy of formation of NH₃ gas?

Round up the following upto three significant figures:
(i) 34.216
(ii) 10.4107
(iii) 0.04597
(iv) 2808