SELECT * FROM question_mgmt as q WHERE id=1809 AND status=1 SELECT id,question_no,question,chapter FROM question_mgmt as q WHERE courseId=3 AND subId=9 AND chapterId=58 and ex_no='2' AND status=1 ORDER BY CAST(question_no AS UNSIGNED)
Three electrolytic cells A,B,C containing solutions of ZnSO4, AgNO3 and CuSO4, respectively are connected in series. A steady current of 1.5 amperes was passed through them until 1.45 g of silver deposited at the cathode of cell B. How long did the current flow? What mass of copper and zinc were deposited?
According to the reaction:
i.e., 108 g of Ag is deposited by 96487 C.
Therefore, 1.45 g of Ag is deposited by = 96487 X 1.45 / 108 C
= 1295.43 C
Given,
Current = 1.5 A
Time =1295.43 /1.5s
= 863.6 s
= 864 s
= 864/ 60
= 14.40 min
Again,
i.e., 2 × 96487 C of charge deposit = 63.5 g of Cu
Therefore, 1295.43 C of charge will deposit = (63.5x1295.43) / (2x96487) g
= 0.426 g of Cu
i.e., 2 × 96487 C of charge deposit = 65.4 g of Zn
Therefore, 1295.43 C of charge will deposit
= (65.4x1295.43) / (2x96487) g
= 0.439 g of Zn
Vapour pressure of pure acetone and chloroform at 328 K are 741.8 mm Hg and 632.8 mm Hg respectively. Assuming that they form ideal solution over the entire range of composition, plot ptotal' pchloroform' and pacetoneas a function of xacetone. The experimental data observed for different compositions of mixture is.
100 ×xacetone |
0 | 11.8 | 23.4 | 36.0 | 50.8 | 58.2 | 64.5 | 72.1 |
pacetone /mm Hg |
0 | 54.9 | 110.1 | 202.4 | 322.7 | 405.9 | 454.1 | 521.1 |
pchloroform/mm Hg |
632.8 | 548.1 | 469.4 | 359.7 | 257.7 | 193.6 | 161.2 | 120.7 |
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