SELECT * FROM question_mgmt as q WHERE id=654 AND status=1 SELECT id,question_no,question,chapter FROM question_mgmt as q WHERE courseId=3 AND subId=9 AND chapterId=56 and ex_no='1' AND status=1 ORDER BY CAST(question_no AS UNSIGNED)
Name the parameters that characterize a unit cell.
A unit cell is the smallest repeating unit in space lattice which when repeated over and over again produces the complete space lattice. It represents the shape of entire crystal. The parameters which characterizes a unit cell are as follows:
1 Relative lengths (distance) of the edges along the three axis (a, b, c). These edges may or may not be equal.
2 Angle between the edges (α, β, γ).The angle α is between the edges b & c, angle β is between the edges c & a, and angle γ is between the edges a & b.
The following results have been obtained during the kinetic studies of the reaction: 2A + B → C + D
Experiment |
A/ mol L - 1 |
B/ mol L - 1 |
Initial rate of formation of D/mol L - 1 min - 1 |
I | 0.1 | 0.1 |
6.0 × 10 - 3 |
II | 0.3 | 0.2 |
7.2 × 10 - 2 |
III | 0.3 | 0.4 |
2.88 × 10 - 1 |
IV | 0.4 | 0.1 |
2.40 × 10 - 2 |
Determine the rate law and the rate constant for the reaction.
Vapour pressure of pure acetone and chloroform at 328 K are 741.8 mm Hg and 632.8 mm Hg respectively. Assuming that they form ideal solution over the entire range of composition, plot ptotal' pchloroform' and pacetoneas a function of xacetone. The experimental data observed for different compositions of mixture is.
100 ×xacetone |
0 | 11.8 | 23.4 | 36.0 | 50.8 | 58.2 | 64.5 | 72.1 |
pacetone /mm Hg |
0 | 54.9 | 110.1 | 202.4 | 322.7 | 405.9 | 454.1 | 521.1 |
pchloroform/mm Hg |
632.8 | 548.1 | 469.4 | 359.7 | 257.7 | 193.6 | 161.2 | 120.7 |
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