Arrange the following (i) CaH2, BeH2& | Class 11 Chemistry Chapter Hydrogen, Hydrogen NCERT Solutions

Question:

Arrange the following

(i) CaH2, BeHand TiHin order of increasing electrical conductance.

(ii) LiH, NaH and CsH in order of increasing ionic character.

(iii) H-H, D-D and F-F in order of increasing bond dissociation enthalpy.

(iv) NaH, MgHand H2O in order of increasing reducing property.

Answer:

(i) The electrical conductance of a molecule depends upon its ionic or covalent nature. Ionic compounds conduct, whereas covalent compounds do not.

BeH2 is a covalent hydride. Hence, it does not conduct. CaH2 is an ionic hydride, which conducts electricity in the molten state. Titanium hydride, TiH2 is metallic in nature and conducts electricity at room temperature. Hence, the increasing order of electrical conductance is as follows:

BeH2 < CaH2 < TiH2

 

(ii) The ionic character of a bond is dependent on the electronegativities of the atoms involved. The higher the difference between the electronegativities of atoms, the smaller is the ionic character.

Electronegativity decreases down the group from Lithium to Caesium. Hence, the ionic character of their hydrides will increase (as shown below).

LiH < NaH < CsH

 

(iii) Bond dissociation energy depends upon the bond strength of a molecule, which in turn depends upon the attractive and repulsive forces present in a molecule.

The bond pair in D-D bond is more strongly attracted by the nucleus than the bond pair in H-H bond. This is because of the higher nuclear mass of D2. The stronger the attraction, the greater will be the bond strength and the higher is the bond dissociation enthalpy. Hence, the bond dissociation enthalpy of D-D is higher than H-H.

However, bond dissociation enthalpy is the minimum in the case of F-F. The bond pair experiences strong repulsion from the lone pairs present on each F-centre.

Therefore, the increasing order of bond dissociation enthalpy is as follows:

F-F < H-H < D-D

 

(iv) Ionic hydrides are strong reducing agents. NaH can easily donate its electrons. Hence, it is most reducing in nature.

Both, MgH2 and H2O are covalent hydrides. H2O is less reducing than MgH2 since the bond dissociation energy of H2O is higher than MgH2.

Hence, the increasing order of the reducing property is

H2O < MgH2 < NaH.


Study Tips for Answering NCERT Questions:

NCERT questions are designed to test your understanding of the concepts and theories discussed in the chapter. Here are some tips to help you answer NCERT questions effectively:

  • Read the question carefully and focus on the core concept being asked.
  • Reference examples and data from the chapter when answering questions about Hydrogen.
  • Review previous year question papers to get an idea of how such questions may be framed in exams.
  • Practice answering questions within the time limit to improve your speed and accuracy.
  • Discuss your answers with your teachers or peers to get feedback and improve your understanding.

Comments

Comment(s) on this Question

Welcome to the NCERT Solutions for Class 11 Chemistry - Chapter . This page offers a step-by-step solution to the specific question from Excercise 1 , Question 16: Arrange the following (i) CaH2, BeH2 and TiH2 in order of increasing electrical conduct....