SELECT * FROM question_mgmt as q WHERE id=1704 AND status=1 SELECT id,question_no,question,chapter FROM question_mgmt as q WHERE courseId=3 AND subId=9 AND chapterId=67 and ex_no='2' AND status=1 ORDER BY CAST(question_no AS UNSIGNED)
Write structural formulas and names of four possible aldol condensation products from propanal and butanal. In each case, indicate which aldehyde acts as nucleophile and which as electrophile.
(i) Taking two molecules of propanal, one which acts as a nucleophile and the other as an electrophile.
(ii) Taking two molecules of butanal, one which acts as a nucleophile and the other as an electrophile.
(iii) Taking one molecule each of propanal and butanal in which propanal acts as a nucleophile and butanal acts as an electrophile.
(iv) Taking one molecule each of propanal and butanal in which propanal acts as an electrophile and butanal acts as a nucleophile.
The following results have been obtained during the kinetic studies of the reaction: 2A + B → C + D
Experiment |
A/ mol L - 1 |
B/ mol L - 1 |
Initial rate of formation of D/mol L - 1 min - 1 |
I | 0.1 | 0.1 |
6.0 × 10 - 3 |
II | 0.3 | 0.2 |
7.2 × 10 - 2 |
III | 0.3 | 0.4 |
2.88 × 10 - 1 |
IV | 0.4 | 0.1 |
2.40 × 10 - 2 |
Determine the rate law and the rate constant for the reaction.
Vapour pressure of pure acetone and chloroform at 328 K are 741.8 mm Hg and 632.8 mm Hg respectively. Assuming that they form ideal solution over the entire range of composition, plot ptotal' pchloroform' and pacetoneas a function of xacetone. The experimental data observed for different compositions of mixture is.
100 ×xacetone |
0 | 11.8 | 23.4 | 36.0 | 50.8 | 58.2 | 64.5 | 72.1 |
pacetone /mm Hg |
0 | 54.9 | 110.1 | 202.4 | 322.7 | 405.9 | 454.1 | 521.1 |
pchloroform/mm Hg |
632.8 | 548.1 | 469.4 | 359.7 | 257.7 | 193.6 | 161.2 | 120.7 |
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