SELECT * FROM question_mgmt as q WHERE id=1662 AND status=1 SELECT id,question_no,question,chapter FROM question_mgmt as q WHERE courseId=3 AND subId=9 AND chapterId=68 and ex_no='1' AND status=1 ORDER BY CAST(question_no AS UNSIGNED) CBSE Free NCERT Solution of 12th chemistry Amines i write structures of different isomeric amines

Question:

(i) Write structures of different isomeric amines corresponding to the molecular formula, C4H11N

(ii) Write IUPAC names of all the isomers.

(iii) What type of isomerism is exhibited by different pairs of amines?

Answer:

(i), (ii) The structures and their IUPAC names of different isomeric amines corresponding to the molecular formula, C4H11N are given below:

(a) CH3-CH2-CH2-CH2-NH2

Butanamine (10)

 

(b)

Butan-2-amine (10)

 

(c)

2-Methylpropanamine (10)

 

(d)

2-Methylpropan-2-amine (10)

 

(e) CH3-CH2-CH2-NH-CH3

N-Methylpropanamine (20)

(f) CH3-CH2-NH-CH2-CH3

N-Ethylethanamine (20)

 

(g)

N-Methylpropan-2-amine (20)

 

(h)

N,N-Dimethylethanamine (3°)

 

(iii) The pairs (a) and (b) and (e) and (g) exhibit position isomerism.

The pairs (a) and (c); (a) and (d); (b) and (c); (b) and (d) exhibit chain isomerism.

The pairs (e) and (f) and (f) and (g) exhibit metamerism.

All primary amines exhibit functional isomerism with secondary and tertiary amines and vice-versa.


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