SELECT * FROM question_mgmt as q WHERE id=1856 AND status=1 SELECT id,question_no,question,chapter FROM question_mgmt as q WHERE courseId=3 AND subId=9 AND chapterId=60 and ex_no='2' AND status=1 ORDER BY CAST(question_no AS UNSIGNED) CBSE Free NCERT Solution of 12th chemistry Surface Chemistry why is adsorption always exothermic

Question:

Why is adsorption always exothermic?

Answer:

Adsorption is always exothermic. This statement can be explained in two ways.

(i) Adsorption leads to a decrease in the residual forces on the surface of the adsorbent. This causes a decrease in the surface energy of the adsorbent. Therefore, adsorption is always exothermic.

(ii) ΔH of adsorption is always negative. When a gas is adsorbed on a solid surface, its movement is restricted leading to a decrease in the entropy of the gas i.e., ΔS is negative. Now for a process to be spontaneous, ΔG should be negative.

ΔG = ΔH - TΔS

Since ΔS is negative, ΔH has to be negative to make ΔG negative. Hence, adsorption is always exothermic.


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