Why does nitrogen show catenation properties less than phosphorus?
Catenation is much more common in phosphorous compounds than in nitrogen compounds. This is because of the relative weakness of the N-N single bond as compared to the P-P single bond. Since nitrogen atom is smaller, there is greater repulsion of electron density of two nitrogen atoms, thereby weakening the N-N single bond.
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Welcome to the NCERT Solutions for Class 12 Chemistry - Chapter . This page offers a step-by-step solution to the specific question from Excercise 2 , Question 14: Why does nitrogen show catenation properties less than phosphorus?....
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