Explain why is ortho nitrophenol more ac | Class 12 Chemistry Chapter Alcohols Phenols and Ethers, Alcohols Phenols and Ethers NCERT Solutions

Question:

Explain why is ortho nitrophenol more acidic than ortho methoxyphenol?

Answer:

The nitro-group is an electron-withdrawing group. The presence of this group in the ortho position decreases the electron density in the O-H bond. As a result, it is easier to lose a proton. Also, the o-nitrophenoxide ion formed after the loss of protons is stabilized by resonance. Hence, ortho nitrophenol is a stronger acid.

On the other hand, methoxy group is an electron-releasing group. Thus, it increases the electron density in the O-H bond and hence, the proton cannot be given out easily.

For this reason, ortho-nitrophenol is more acidic than ortho-methoxyphenol.


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Comments

  • Abhay
  • 2019-11-07 10:03:30

Great


  • nikhil
  • 2019-11-06 16:29:37

thanks sir


  • Theju
  • 2019-07-08 19:07:12

Thanks


  • Poonam
  • 2019-05-19 15:53:34

Thanks🙏🙇


  • Shikha singh
  • 2019-05-19 11:24:04

nice answer but not perfectly shown


  • George Ghosh
  • 2019-03-10 12:19:29

Very good answer


  • Pallab chanda
  • 2019-02-19 19:13:16

Very helpful


  • Pragya
  • 2019-02-14 09:52:14

Thnkuuuuuuu it's very useful


  • Khushi
  • 2019-01-08 10:24:18

Perfect answer ...thanx


  • Dibya ranjan samantaray
  • 2018-11-02 15:28:37

Thanks its a great help to me


Comment(s) on this Question

Welcome to the NCERT Solutions for Class 12 Chemistry - Chapter . This page offers a step-by-step solution to the specific question from Excercise 2 , Question 15: Explain why is ortho nitrophenol more acidic than ortho methoxyphenol?....