SELECT * FROM question_mgmt as q WHERE id=1948 AND status=1 SELECT id,question_no,question,chapter FROM question_mgmt as q WHERE courseId=3 AND subId=9 AND chapterId=64 and ex_no='2' AND status=1 ORDER BY CAST(question_no AS UNSIGNED)
Discuss the nature of bonding in metal carbonyls.
The metal-carbon bonds in metal carbonyls have both σ and π characters. A σ bond is formed when the carbonyl carbon donates a lone pair of electrons to the vacant orbital of the metal. A π bond is formed by the donation of a pair of electrons from the filled metal d orbital into the vacant anti-bonding π orbital (also known as back bonding of the carbonyl group). The σ bond strengthens the π bond and vice-versa. Thus, a synergic effect is created due to this metal-ligand bonding. This synergic effect strengthens the bond between CO and the metal.
The rate constant for the decomposition of N2O5 at various temperatures is given below:
T/°C |
0 | 20 | 40 | 60 | 80 |
105 X K /S-1 |
0.0787 | 1.70 | 25.7 | 178 | 2140 |
Draw a graph between ln k and 1/T and calculate the values of A and Ea.
Predict the rate constant at 30 º and 50 ºC.
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