SELECT * FROM question_mgmt as q WHERE id=1949 AND status=1 SELECT id,question_no,question,chapter FROM question_mgmt as q WHERE courseId=3 AND subId=9 AND chapterId=64 and ex_no='2' AND status=1 ORDER BY CAST(question_no AS UNSIGNED)

Question:

Give the oxidation state, d-orbital occupation and coordination number of the central metal ion in the following complexes:

(i) K3[Co(C2O4)3]

(ii) cis-[Cr(en)2Cl2]Cl

(iii) (NH4)2[CoF4]

(iv) [Mn(H2O)6]SO4

Answer:

(i) K3[Co(C2O4)3]

The central metal ion is Co.

Its coordination number is 6.

The oxidation state can be given as:

x - 6 = -3

x = + 3

The d orbital occupation for Co3+ is t2g6eg0.

 

(ii) cis-[Cr(en)2Cl2]Cl

The central metal ion is Cr.

The coordination number is 6.

The oxidation state can be given as:

x + 2(0) + 2(-1) = +1

x - 2 = +1

x = +3

The d orbital occupation for Cr3+ is t2g3.

 

(iii) (NH4)2[CoF4]

The central metal ion is Co.

The coordination number is 4.

The oxidation state can be given as:

x - 4 = -2

x = + 2

The d orbital occupation for Co2+ is eg4 t2g3.

 

(iv) [Mn(H2O)6]SO4

The central metal ion is Mn.

The coordination number is 6.

The oxidation state can be given as:

x + 0 = +2

x = +2

The d orbital occupation for Mn is t2g3 eg2.


< Previous Question

Next Question >

SELECT ex_no,question,question_no,id,chapter FROM question_mgmt as q WHERE courseId='3' AND subId='9' AND ex_no!=0 AND status=1 and id!=1949 ORDER BY views desc, last_viewed_on desc limit 0,10

  • Popular questions of class 12 Chemistry

SELECT ex_no,question,question_no,id,chapter FROM question_mgmt as q WHERE courseId='3' AND subId='9' AND ex_no!=0 AND status=1 and id!=1949 ORDER BY last_viewed_on desc limit 0,10

  • Recently Viewed Questions of Class 12 Chemistry

Comments

  • Answered by Ekta Mehta
  • 4 months ago

Taking Screenshots on your Samsung Galaxy M31s is very easy and quick.

  • Answered by Ekta Mehta
  • 4 months ago

Taking Screenshots on your Samsung Galaxy M31s is very easy and quick.

  • Answered by Ekta Mehta
  • 4 months ago

Taking Screenshots on your Samsung Galaxy M31s is very easy and quick.

Comment(s) on this Question


Important links

Quick Links

Resources

Support