A solution of Ni(NO3)2 is electrolysed b | Class 12 Chemistry Chapter Electrochemistry, Electrochemistry NCERT Solutions

How the following conversions can be carried out?

(i) Propene to propan-1-ol

(ii) Ethanol to but-1-yne

(iii) 1-Bromopropane to 2-bromopropane

(iv) Toluene to benzyl alcohol

(v) Benzene to 4-bromonitrobenzene

(vi) Benzyl alcohol to 2-phenylethanoic acid

(vii) Ethanol to propanenitrile

(viii) Aniline to chlorobenzene

(ix) 2-Chlorobutane to 3, 4-dimethylhexane

(x) 2-Methyl-1-propene to 2-chloro-2-methylpropane

(xi) Ethyl chloride to propanoic acid

(xii) But-1-ene to n-butyliodide

(xiii) 2-Chloropropane to 1-propanol

(xiv) Isopropyl alcohol to iodoform

(xv) Chlorobenzene to p-nitrophenol

(xvi) 2-Bromopropane to 1-bromopropane

(xvii) Chloroethane to butane

(xviii) Benzene to diphenyl

(xix) tert-Butyl bromide to isobutyl bromide

(xx) Aniline to phenylisocyanide

Give simple chemical tests to distinguish between the following pairs of compounds.

(i) Propanal and Propanone

(ii) Acetophenone and Benzophenone

(iii) Phenol and Benzoic acid

(iv) Benzoic acid and Ethyl benzoate

(v) Pentan-2-one and Pentan-3-one

(vi) Benzaldehyde and Acetophenone

(vii) Ethanal and Propanal

A 5% solution (by mass) of cane sugar in water has freezing point of 271 K. Calculate the freezing point of 5% glucose in water if freezing point of pure water is 273.15 K.

A solution of glucose in water is labelled as 10% w/w, what would be the molality and mole fraction of each component in the solution? If the density of solution is 1.2 g mL^-1, then what shall be the molarity of the solution?

Henry's law constant for CO₂ in water is 1.67 x 10⁸Pa at 298 K. Calculate the quantity of CO₂in 500 mL of soda water when packed under 2.5 atm CO₂ pressure at 298 K.

Calculate the mass of a non-volatile solute (molar mass 40 g mol^-1) which should be dissolved in 114 g octane to reduce its vapour pressure to 80%.

The vapour pressure of pure liquids A and B are 450 and 700 mm Hg respectively, at 350 K. Find out the composition of the liquid mixture if total vapour pressure is 600 mm Hg. Also find the composition of the vapour phase.

Calculate the mole fraction of benzene in solution containing 30% by mass in carbon tetrachloride.

How many mL of 0.1 M HCl are required to react completely with 1 g mixture of Na₂CO₃ and NaHCO₃ containing equimolar amounts of both?

If NaCl is doped with 10^-3mol % of SrCl₂, what is the concentration of cation vacancies?

Among the isomeric alkanes of molecular formula C₅H₁₂, identify the one that on photochemical chlorination yields

(i) A single monochloride.

(ii) Three isomeric monochlorides.

(iii) Four isomeric monochlorides.

Calculate the potential of hydrogen electrode in contact with a solution whose pH is 10.

Show how each of the following compounds can be converted to benzoic acid.

(i) Ethylbenzene        (ii) Acetophenone

(iii) Bromobenzene    (iv) Phenylethene (Styrene)

The conductivity of 0.20 M solution of KCl at 298 K is 0.0248 Scm^-1. Calculate its molar conductivity.

Name a sweetening agent used in the preparation of sweets for a diabetic patient.

What may be the stable oxidation state of the transition element with the following d electron configurations in the ground state of their atoms :

3d³, 3d⁵, 3d⁸ and 3d⁴?

What is meant by positive & negative deviations from raoult’s law & how is the sign of ΔmixH related to positive & negative deviations from Raoult’s law?

Using the standard electrode potentials given in Table 3.1, predict if the reaction between the following is feasible:

(i) Fe³⁺(aq) and I^-(aq)

(ii) Ag⁺ (aq) and Cu(s)

(iii) Fe³⁺ (aq) and Br^- (aq)

(iv) Ag(s) and Fe³⁺ (aq)

(v) Br₂ (aq) and Fe²⁺ (aq).

Calculate

(a) molality

(b) molarity and

(c) mole

fraction of KI if the density of 20% (mass/mass) aqueous KI is 1.202 g mL^-1.

What is the role of graphite rod in the electrometallurgy of aluminium?