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Is there any change in the hybridisation of B and N atoms as a result ...

Is there any change in the hybridisation | Class 11 Chemistry Chapter Chemical Bonding and Molecular Structure, Chemical Bonding and Molecular Structure NCERT Solutions

Welcome to the NCERT Solutions for Class 11 Chemistry - Chapter Chemical Bonding and Molecular Structure. This page offers a step-by-step solution to the specific question from Exercise 1, Question 26: . With detailed answers and explanations for each chapter, students can strengthen their understanding and prepare confidently for exams. Ideal for CBSE and other board students, this resource will simplify your study experience.

Question 26:

Is there any change in the hybridisation of B and N atoms as a result of the following reaction?

BF₃ + NH₃ → F₃B.NH₃

Answer:

The atomic number of boron is 5 & its electronic configuration in ground state is 1s²2s² 2p¹, & in excited state is 1s²2s¹ 2p², this means its one s & 2 p orbital will take part in hybridization to form sp² hybrid orbital.

Similarly N atom has atomic number of 7, with electronic configuration of 1s²2s² 2p³ in its ground state & in it excited state it has sp³ hybridization.

Now according to the question Boron & Nitrogen in reactant stage has sp² & sp³ hybridization respectively, but on the product side an adduct is formed, wherein Boron has changed it s hybridization to sp³ while Nitrogen remains in same sp³ hybridization

Other Questions of Chapter Chemical Bonding and Molecular Structure

Describe the change in hybridisation (if any) of the Al atom in the following reaction.

Write Lewis symbols for the following atoms and ions:

S and S2–; Al and Al3+; H and H–

What is meant by the term bond order? Calculate the bond order of: N₂, O₂,O₂⁺,and O₂^-.

Define hydrogen bond. Is it weaker or stronger than the van der Waals forces?

Describe the hybridisation in case of PCl₅. Why are the axial bonds longer as compared to equatorial bonds?

Write the significance of a plus and a minus sign shown in representing the orbitals.

Which hybrid orbitals are used by carbon atoms in the following molecules?

(a)CH₃–CH₃;

(b) CH₃–CH=CH₂;

(d) CH₃-CHO

(e) CH₃COOH

Considering x-axis as the internuclear axis which out of the following will not form a sigma bond and why?

(a) 1s and 1s

(b) 1s and 2p_x

(d) 1s and 2s.

What is the total number of sigma and pi bonds in the following molecules?

(a) C₂H₂ (b) C₂H₄

What is meant by hybridisation of atomic orbitals? Describe the shapes of sp, sp^₂, sp³hybrid orbitals.

Popular questions of class 11 Chemistry

Calculate the amount of carbon dioxide that could be produced when

(i) 1 mole of carbon is burnt in air.

(ii) 1 mole of carbon is burnt in 16 g of dioxygen.

(iii) 2 moles of carbon are burnt in 16 g of dioxygen.

The mass of an electron is 9.1 × 10^–31 kg. If its K.E. is 3.0 × 10^–25 J, calculate its wavelength.

Calculate the wavelength of an electron moving with a velocity of 2.05 × 10⁷ ms^–1.

Balance the following redox reactions by ion – electron method :

(a) MnO₄^–(aq) + I^–(aq) → MnO_{2 (s)} + I_2(s) (in basic medium)

(b) MnO₄ ^– (aq) + SO_{2 (g)}→ Mn²⁺ (aq) + HSO₄^– (aq) (in acidic solution)

(d) Cr₂O₇ ^2– + SO_2(g) → Cr³⁺ _(aq) + SO₄^2–(aq) (in acidic solution)

In a process, 701 J of heat is absorbed by a system and 394 J ofwork is done by the system. What is the change in internal energy for the process?

What will be the minimum pressure required to compress 500 dm³ of air at 1 bar to 200 dm³ at 30°C?

In a reaction A + B2 → AB2 Identify the limiting reagent, if any, in the following reaction mixtures.

(i) 300 atoms of A + 200 molecules of B

(ii) 2 mol A + 3 mol B

(iii) 100 atoms of A + 100 molecules of B

(iv) 5 mol A + 2.5 mol B

(v) 2.5 mol A + 5 mol B

At 0°C, the density of a certain oxide of a gas at 2 bar is same as that of dinitrogen at 5 bar. What is the molecular mass of the oxide?

Which one of the following will have largest number of atoms?

(i) 1 g Au (s)

(ii) 1 g Na (s)

(iii) 1 g Li (s)

(iv) 1 g of Cl2(g)

Density of a gas is found to be 5.46 g/dm³ at 27 °C at 2 bar pressure. What will be its density at STP?

Recently Viewed Questions of Class 11 Chemistry

How would you convert the following compounds into benzene?

(i) Ethyne (ii) Ethene (iii) Hexane

Explain structures of diborane and boric acid.

For the following equilibrium, K_c= 6.3 × 10¹⁴ at 1000 K

NO (g) + O₃ (g) ↔ NO₂ (g) + O₂(g)

Both the forward and reverse reactions in the equilibrium are elementary bimolecular reactions. What is K_c, for the reverse reaction?

Find out the value of K_c for each of the following equilibria from the value of K_p:

(i) 2NOCl (g) ↔ 2NO (g) + Cl₂ (g); Kp = 1.8 × 10^–2 at 500 K

(ii) CaCO₃ (s) ↔ CaO(s) + CO₂(g); Kp = 167 at 1073 K

In a reaction A + B2 → AB2 Identify the limiting reagent, if any, in the following reaction mixtures.

(i) 300 atoms of A + 200 molecules of B

(ii) 2 mol A + 3 mol B

(iii) 100 atoms of A + 100 molecules of B

(iv) 5 mol A + 2.5 mol B

(v) 2.5 mol A + 5 mol B

Find energy of each of the photons which

(i) correspond to light of frequency 3× 1015 Hz.

(ii) have wavelength of 0.50 Å.

Calculate the number of kJ of heat necessary to raise the temperature of 60.0 g of aluminium from 35°C to 55°C. Molar heat capacity of Al is 24 J mol^–1 K^–1.

A liquid is in equilibrium with its vapour in a sealed container at a fixed temperature. The volume of the container is suddenly increased.
a) What is the initial effect of the change on vapour pressure?
b) How do rates of evaporation and condensation change initially?
c) What happens when equilibrium is restored finally and what will be the final vapour pressure?

Calculate the amount of carbon dioxide that could be produced when

(i) 1 mole of carbon is burnt in air.

(ii) 1 mole of carbon is burnt in 16 g of dioxygen.

(iii) 2 moles of carbon are burnt in 16 g of dioxygen.

While sulphur dioxide and hydrogen peroxide can act as oxidising as well as reducing agents in their reactions, ozone and nitric acid act only as oxidants. Why?

Study Tips for Answering NCERT Questions:

NCERT questions are designed to test your understanding of the concepts and theories discussed in the chapter. Here are some tips to help you answer NCERT questions effectively:

Read the question carefully and focus on the core concept being asked.
Reference examples and data from the chapter when answering questions about Chemical Bonding and Molecular Structure.
Review previous year question papers to get an idea of how such questions may be framed in exams.
Practice answering questions within the time limit to improve your speed and accuracy.
Discuss your answers with your teachers or peers to get feedback and improve your understanding.

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Comments

Awer
Sep 22, 2019

You explained but no one understands no offence

vishnu
Dec 25, 2018

i dunno understand that ???

Ramesh Kumar
May 30, 2018

How can we find hybridization of F3B.NH3

Vassudev
Aug 26, 2017

There is no change in both the case for hybridisation. This statement is given in a guide.....Which one is true? Why?