A liquid is in equilibrium with its vapo | Class 11 Chemistry Chapter Equilibrium, Equilibrium NCERT Solutions

Question:

A liquid is in equilibrium with its vapour in a sealed container at a fixed temperature. The volume of the container is suddenly increased.
a) What is the initial effect of the change on vapour pressure?
b) How do rates of evaporation and condensation change initially?
c) What happens when equilibrium is restored finally and what will be the final vapour pressure?

Answer:

Vapour pressure is the pressure exerted by the vapour in equilibrium with the liquid at a fixed temperature.

(a) If the volume of the container is suddenly increased, then the vapour pressure would decrease initially. This is because the amount of vapour remains the same, but the volume increases suddenly. As a result, the same amount of vapour is distributed in a larger volume.

(b) Since the temperature is constant, the rate of evaporation also remains constant. When the volume of the container is increased, the density of the vapour phase decreases. As a result, the rate of collisions of the vapour particles also decreases. Hence, the rate of condensation decreases initially.

(c) When equilibrium is restored finally, the rate of evaporation becomes equal to the rate of condensation. In this case, only the volume changes while the temperature remains constant. The vapour pressure depends on temperature and not on volume. Hence, the final vapour pressure will be equal to the original vapour pressure of the system.


Study Tips for Answering NCERT Questions:

NCERT questions are designed to test your understanding of the concepts and theories discussed in the chapter. Here are some tips to help you answer NCERT questions effectively:

  • Read the question carefully and focus on the core concept being asked.
  • Reference examples and data from the chapter when answering questions about Equilibrium.
  • Review previous year question papers to get an idea of how such questions may be framed in exams.
  • Practice answering questions within the time limit to improve your speed and accuracy.
  • Discuss your answers with your teachers or peers to get feedback and improve your understanding.

Comments

  • vipul mishra
  • 2019-12-13 15:23:43

answer are too long so make this short


  • Amrit
  • 2019-11-06 17:02:28

Good


  • Akash
  • 2019-10-21 18:56:06

Nice


  • nice
  • 2018-11-09 14:29:56

Nice


Comment(s) on this Question

Welcome to the NCERT Solutions for Class 11 Chemistry - Chapter . This page offers a step-by-step solution to the specific question from Excercise 1 , Question 1: A liquid is in equilibrium with its vapour in a sealed container at a fixed temperature. The volume ....