Calculate the oxidation number of sulphu | Class 11 Chemistry Chapter Redox Reactions, Redox Reactions NCERT Solutions

Question:

Calculate the oxidation number of sulphur, chromium and nitrogen in H2SO5, Cr2O2- 7 and NO 3. Suggest structure of these compounds. Count for the fallacy.

Answer:

(a) H2SO5

Let assume oxidation number of S is x.

We know that,

Oxidation number of H = +1

Oxidation number of O = -2

Then we have

2(+1) + (x) + 5 (-2) = 0

⇒ 2 + x - 10 = 0

⇒ x  =  +8

However, the O.N. of S cannot be +8. S has six valence electrons. Therefore, the O.N. of S cannot be more than +6. The structure of H2SO5 is shown as follows:

Now , 2(+1) + 1(x) + 3(-2)  + 2 (-1) = 0

⇒ 2 + x - 6 -2 = 0

⇒ x  =  +6

Therefore, the O.N. of S is +6.

 

(b) Cr2O2-7

Let assume oxidation number of Cr is x.

We know that,

Oxidation number of O = -2

Then we have

 2(x) + 7 (-2) =  -2

⇒ 2x  -14  = -2

⇒ 2x   =  +12

x  = +6

Here, there is no fallacy about the O.N. of Cr in Cr2O72-

The structure of Cr2O72- is shown as follows: 

Here, each of the two Cr atoms exhibits the O.N. of +6. 

 

(c) NO3-

Let assume oxidation number of N is x.

We know that,

Oxidation number of O = -2

Then we have

1(x) + 3 (-2) =  -1

⇒ x  - 6 = -1

⇒ x   =  +5

Here, there is no fallacy about the O.N. of N in NO3-

The structure of  NO3is shown as follows:

The N atom exhibits the O.N. of +5. 

 


Study Tips for Answering NCERT Questions:

NCERT questions are designed to test your understanding of the concepts and theories discussed in the chapter. Here are some tips to help you answer NCERT questions effectively:

  • Read the question carefully and focus on the core concept being asked.
  • Reference examples and data from the chapter when answering questions about Redox Reactions.
  • Review previous year question papers to get an idea of how such questions may be framed in exams.
  • Practice answering questions within the time limit to improve your speed and accuracy.
  • Discuss your answers with your teachers or peers to get feedback and improve your understanding.

Comments

Comment(s) on this Question

Welcome to the NCERT Solutions for Class 11 Chemistry - Chapter . This page offers a step-by-step solution to the specific question from Excercise 1 , Question 5: Calculate the oxidation number of sulphur, chromium and nitrogen in H2SO5, Cr2O2- 7 and NO– 3.....